In this post, we’re diving back into the world of sphere packings, focusing on the space groups and . Feel free to check out an earlier discussion on Densest P1, P-1 and P21/c packings of spheres. Both of these groups reach the packing density of .
The densest packing almost identical to the group. Even though they belong to different crystal systems—triclinic for and monoclinic for —they share the same unit cell parameters: , , and . Here’s a snapshot of what this packing looks like:
Next up is the space group, which also falls under the monoclinic category. This group is a bit more complex, with eight symmetry operations. Its densest packing has unit cell parameters of , , and . Check out the illustration below of the densest packing configuration:
So far, we’ve seen that the optimal packing density for the space groups , , , , and matches the general optimal sphere packing density. This isn’t too surprising since these groups are all related to the Hexagonal Closed Packed structure, via group – subgroup relations. Interestingly, these space groups are among the top ten of the most frequently occurring in the Cambridge Structural Database, making up 74% of its entries.